{2,2′-[(1,2-Dicyanoethene-1,2-diyl)bis(nitrilomethanylylidyne)]diphenolato-κ4 O,N,N′,O′}(methanol-κO)zinc
نویسندگان
چکیده
In the title complex, [Zn(C18H10N4O2)(CH4O)], the Zn(2+) cation is located on a mirror plane and is coordinated by a tetradentate Schiff base ligand anion (L (2-)) and a methanol mol-ecule. The Zn(2+) cation is surrounded by two N atoms and two O atoms from L (2-), in a nearly planar configuration, and one methanol O atom, forming a slightly distorted square-pyramidal geometry. The methanol molecule is disordered over two sets of sites in a 0.5:0.5 ratio. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into chains parallel to [001].
منابع مشابه
Chlorido[2,2′-[1,2-phenylenebis(nitrilomethanylylidyne)]diphenolato-κ4 O,N,N′,O′]manganese(III) methanol monosolvate
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013